I first discovered Maryville, TN on a day trip from Knoxville. The historic Main Street is lovely to visit with local boutiques, cafés, breweries, and public art installations. I enjoyed walking along the paved Maryville-Alcoa Greenway with wooded are for shade.
If you are traveling by car, Maryville is located off US-129 and US-321. The drive from Knoxville will take you about 30 minutes. You'll be 45 minutes from the Great Smoky Mountains National Park entrance.
I like staying at Luxbury Inn & Suites because they have kitchens. RT Lodge is a good choice if you want fine dining.
Best Things to Do in Maryville, TN
First: Stroll Through Scenic Paths at Bicentennial Greenbelt Park
Second: Relax at Blue Goose Farm and Vineyards
Third: Catch a Show at the Historic Capitol Theatre
Fourth: If You Love Early American History, Visit the Sam Houston Historic Schoolhouse
In Summary...
(and if you want to revisit my photo journey)